Category Archives: nonequilibrium physics

Weak additivity principle for current statistics in d-dimensions

Carlos Pérez-Espigares, Pedro L. Garrido, Pablo I. Hurtado

screenshot_14The additivity principle (AP) allows to compute the current distribution in many one-dimensional (1d) nonequilibrium systems. Here we extend this conjecture to general d-dimensional driven diffusive systems, and validate its predictions against both numerical simulations of rare events and microscopic exact calculations of three paradigmatic models of diffusive transport in d=2. Crucially, the existence of a structured current vector field at the fluctuating level, coupled to the local mobility, turns out to be essential to understand current statistics in d>1. We prove that, when compared to the straightforward extension of the AP to high-d, the so-called weak AP always yields a better minimizer of the macroscopic fluctuation theory action for current statistics.

Phys. Rev. E 93, 040103(R) (2016); arXiv:1511.08373

Statistics of the dissipated energy in driven diffusive systems

A. Lasanta, Pablo I. Hurtado, A. Prados

screenshot_56Understanding the physics of non-equilibrium systems remains as one of the major open questions in statistical physics. This problem can be partially handled by investigating macroscopic fluctuations of key magnitudes that characterise the non-equilibrium behaviour of the system of interest; their statistics, associated structures and microscopic origin. During the last years, some new general and powerful methods have appeared to delve into fluctuating behaviour that have drastically changed the way to address this problem in the realm of diffusive systems: macroscopic fluctuation theory (MFT) and a set of advanced computational techniques that make it possible to measure the probability of rare events. Notwithstanding, a satisfactory theory is still lacking in a particular case of intrinsically non-equilibrium systems, namely those in which energy is not conserved but dissipated continuously in the bulk of the system (e.g. granular media). In this work, we put forward the dissipated energy as a relevant quantity in this case and analyse in a pedagogical way its fluctuations, by making use of a suitable generalisation of macroscopic fluctuation theory to driven dissipative media.

Eur. Phys. J. E 39, 35 (2016); arXiv:1508.07635

Violation of universality in anomalous Fourier’s law

Pablo I. Hurtado, Pedro L. Garrido

fig3Since the discovery of long-time tails, it has been clear that Fourier’s law in low dimensions is typically anomalous, with a size-dependent heat conductivity, though the nature of the anomaly remains puzzling. The conventional wisdom, supported by recent results from nonlinear fluctuating hydrodynamics, is that the anomaly is universal in 1d momentum-conserving systems and belongs in the Kardar-Parisi-Zhang universality class. Here we challenge this picture by using a novel scaling method to show unambiguously that universality breaks down in the paradigmatic 1d diatomic hard-point fluid. Hydrodynamic profiles for a broad set of gradients, densities and sizes all collapse onto an universal master curve, showing that (anomalous) Fourier’s law holds even deep into the nonlinear regime. This allows to solve the macroscopic transport problem for this model, a solution which compares flawlessly with data and, interestingly, implies the existence of a bound on the heat current in terms of pressure. These results question the use of standard fluctuating hydrodynamics to understand anomalous Fourier’s law in 1d, offering a new perspective on transport and its anomalies in low dimensions.

Nature Sci. Rep. 6, 38823 (2016); arXiv:1506.03234

Probing local equilibrium in nonequilibrium fluids

J.J. del Pozo, P.L. Garrido, P.I. Hurtado

We use extensive computer simulations to probe local thermodynamic equilibrium (LTE) in a quintessential model fluid, the two-dimensional hard-disks system. We show that macroscopic LTE is a property much stronger than previously anticipated, even in the presence of important finite size effects, revealing a remarkable bulk-boundary decoupling phenomenon in fluids out of equilibrium. This allows us to measure the fluid’s equation of state in simulations far from equilibrium, with an excellent accuracy comparable to the best equilibrium simulations. Subtle corrections to LTE are found in the fluctuations of the total energy which strongly point out to the nonlocality of the nonequilibrium potential governing the fluid’s macroscopic behavior out of equilibrium.

Phys. Rev. E 92, 022117 (2015); arXiv:1407.3113

Scaling laws and bulk-boundary decoupling in heat flow

J.J. del Pozo, P.L. Garrido, P.I. Hurtado

When driven out of equilibrium by a temperature gradient, fluids respond by developing a nontrivial, inhomogeneous structure according to the governing macroscopic laws. Here we show that such structure obeys strikingly simple scaling laws arbitrarily far from equilibrium, provided that both macroscopic local equilibrium and Fourier’s law hold. Extensive simulations of hard disk fluids confirm the scaling laws even under strong temperature gradients, implying that Fourier’s law remains valid in this highly nonlinear regime, with putative corrections absorbed into a nonlinear conductivity functional. In addition, our results show that the scaling laws are robust in the presence of strong finite-size effects, hinting at a subtle bulk-boundary decoupling mechanism which enforces the macroscopic laws on the bulk of the finite-sized fluid. This allows to measure for the first time the marginal anomaly of the heat conductivity predicted for hard disks.

Additional material: video demonstrating the scaling procedure (credit: J. del Pozo 2014)

Phys. Rev. E 91, 032116 (2015); arXiv:1401.5244

Thermodynamics of currents in nonequilibrium diffusive systems: theory and simulation

Pablo I. Hurtado, Carlos P. Espigares, Jesus J. del Pozo, Pedro L. Garrido

screenshot_16Understanding the physics of nonequilibrium systems remains as one of the major challenges of theoretical physics. This problem can be cracked in part by investigating the macroscopic fluctuations of the currents characterizing nonequilibrium behavior, their statistics and associated structures. This fundamental line of research has been severely hampered by the overwhelming complexity of this problem. However, during the last years two new general methods have appeared to investigate fluctuating behavior that are changing radically our understanding of nonequilibrium physics: a powerful macroscopic fluctuation theory (MFT) and a set of advanced computational techniques to measure rare events. In this work we study the statistics of current fluctuations in nonequilibrium diffusive systems, using macroscopic fluctuation theory as theoretical framework, and advanced Monte Carlo simulations of several stochastic lattice gases as a laboratory to test the emerging picture. Our quest will bring us from (1) the confirmation of an additivity conjecture in one and two dimensions, which considerably simplifies the MFT complex variational problem to compute the thermodynamics of currents, to (2) the discovery of novel isometric fluctuation relations, which opens an unexplored route toward a deeper understanding of nonequilibrium physics by bringing symmetry principles to the realm of fluctuations, and to (3) the observation of coherent structures in fluctuations, which appear via dynamic phase transitions involving a spontaneous symmetry breaking event at the fluctuating level. The clear-cut observation, measurement and characterization of these unexpected phenomena, well described by MFT, strongly support this theoretical scheme as the natural theory to understand the thermodynamics of currents in nonequilibrium diffusive media, opening new avenues of research in nonequilibrium physics.

J. Stat. Phys. 154, 214 (2014); arXiv:1312.1246

Symmetry and the thermodynamics of currents in open quantum systems

Daniel Manzano, Pablo I. Hurtado

Symmetry is a powerful concept in physics, and its recent application to understand nonequilibrium behavior is providing deep insights and groundbreaking exact results. Here we show how to harness symmetry to control transport and statistics in open quantum systems. Such control is enabled by a first-order-type dynamic phase transition in current statistics and the associated coexistence of different transport channels (or nonequilibrium steady states) classified by symmetry. Microreversibility then ensues, via the Gallavotti-Cohen fluctuation theorem, a twin dynamic phase transition for rare current fluctuations. Interestingly, the symmetry present in the initial state is spontaneously broken at the fluctuating level, where the quantum system selects the symmetry sector that maximally facilitates a given fluctuation. We illustrate these results in a qubit network model motivated by the problem of coherent energy harvesting in photosynthetic complexes, and introduce the concept of a symmetry-controlled quantum thermal switch, suggesting symmetry-based design strategies for quantum devices with controllable transport properties.

Phys. Rev. B 90, 125138 (2014); arXiv:1310.7370

Nonlinear driven diffusive systems with dissipation: fluctuating hydrodynamics

A. Prados, A. Lasanta, Pablo I. Hurtado

screenshot_20We consider a general class of nonlinear diffusive models with bulk dissipation and boundary driving, and derive its hydrodynamic description in the large size limit. Both the average macroscopic behavior and the fluctuating properties of the hydrodynamic fields are obtained from the microscopic dynamics. This analysis yields a fluctuating balance equation for the local energy density at the mesoscopic level, characterized by two terms: (i) a diffusive term, with a current that fluctuates around its average behavior given by nonlinear Fourier’s law, and (ii) a dissipation term which is a general function of the local energy density. The quasi-elasticity of microscopic dynamics, required in order to have a nontrivial competition between diffusion and dissipation in the macroscopic limit, implies a noiseless dissipation term in the balance equation, so dissipation fluctuations are enslaved to those of the density field. The microscopic complexity is thus condensed in just three transport coefficients, the diffusivity, the mobility and a new dissipation coefficient, which are explicitly calculated within a local equilibrium approximation. Interestingly, the diffusivity and mobility coefficients obey an Einstein relation despite the fully nonequilibrium character of the problem. The general theory here presented is applied to a particular albeit broad family of systems, the simplest nonlinear dissipative variant of the so-called KMP model for heat transport. The theoretical predictions are compared to extensive numerical simulations, and an excellent agreement is found.

Phys. Rev. E 86, 031134 (2012); arXiv:1207.5021

Compact Waves in Microscopic Nonlinear Diffusion

Pablo I. Hurtado, Paul L. Krapivsky

We analyze the spread of a localized peak of energy into vacuum for nonlinear diffusive processes. In contrast with standard diffusion, the nonlinearity results in a compact wave with a sharp front separating the perturbed region from vacuum. In d spatial dimensions, the front advances as t^{1/(2+da)} according to hydrodynamics, with a the nonlinearity exponent. We show that fluctuations in the front position grow as ∼ tμη, where μ<1/(2+da) is a new exponent that we measure and η is a random variable whose distribution we characterize. Fluctuating corrections to hydrodynamic profiles give rise to an excess penetration into vacuum, revealing scaling behaviors and robust features. We also examine the discharge of a nonlinear rarefaction wave into vacuum. Our results suggest the existence of universal scaling behaviors at the fluctuating level in nonlinear diffusion.

Phys. Rev. E 85, 060103(R) (2012); arXiv:1112.5988

Spontaneous Symmetry Breaking at the Fluctuating Level

Pablo I. Hurtado, Pedro L. Garrido

Phase transitions not allowed in equilibrium steady states may happen however at the fluctuating level. We observe for the first time this striking and general phenomenon measuring current fluctuations in an isolated diffusive system. While small fluctuations result from the sum of weakly-correlated local events, for currents above a critical threshold the system self-organizes into a coherent traveling wave which facilitates the current deviation by gathering energy in a localized packet, thus breaking translation invariance. This results in Gaussian statistics for small fluctuations but non-Gaussian tails above the critical current. Our observations, which agree with predictions derived from hydrodynamic fluctuation theory, strongly suggest that rare events are generically associated with coherent, self-organized patterns which enhance their probability.

Phys. Rev. Lett. 107, 180601 (2011); arXiv:1106.0690